Good bakers know how to follow recipes. Great bakers know how to tweak them – how to deviate subtly from the printed word and create something that’s not just tasty but tailor-made to your palate. The line between good and great is surprising easy to navigate when it comes to chocolate chip cookies. All you need is a little cookie science and a friendly guide to show you the way.

In our case, that guide is Jocelyn, a top-notch baker who develops recipes in King Arthur Flour’s test kitchen. She knows that just a few simple changes can turn a regular chocolate chip cookie into one that’s extra-crunchy, extra-chewy, or extra-cakey.

Cookie Science via @kingarthurflour

I caught up with Jocelyn (with a very helpful assist from our own Dr. Andrea Brown) to understand the yummy science behind personalizing each batch of cookies.

For simplicity’s sake, let’s focus on Everyone's Favorite Chocolate Chip Cookie, a new mix that Jocelyn developed for King Arthur Flour’s Essential Goodness line. She’ll share exact measurements for personalizing that mix, but the basic principles apply to pretty much any chocolate chip cookie recipe.

Cookie Science via @kingarthurflour

How to make extra-crunchy cookies

If you’re making Everyone’s Favorite Chocolate Chip Cookie, add 2 tablespoons granulated sugar and bake for 2 to 4 extra minutes.

What does the extra sugar do?

Although sugar may seem like a fairly simple ingredient, it plays a very important and complex role in cookie dough. It contributes to both texture and flavor in many ways: it melts in the heat of the oven to increase spread, and it creates little air pockets in the dough to expand and make cookies rise. Sugar also caramelizes and participates in Maillard reactions to add both color and additional notes to the flavor, and it recrystallizes upon cooling to give the cookies crispy texture.

Maillard reactions are when amino acids react with sugars to give you the brown color and caramelized flavor in baked goods.

When adding an extra two tablespoons of granulated sugar here, you increase the ratio of sugar to fat and flour in the cookie. This will result in a bit more spread, a larger surface area and more material to caramelize and react and, of course, a little bit of extra sweetness as well, which never hurts.

You may notice that the cookies won’t be crispy immediately out of the oven; that happens later. While the exact science of cookie cooling is still somewhat of a mystery, one theory is that as the molten sugar retreats to its crystalline structure and solidifies, the cookie becomes crispy as opposed to bendy. Working with that theory, we can then understand why the more sugar present to recrystallize, the more snap your cookie will have.

How does granulated sugar act differently than brown sugar?

Granulated sugar contains little to no “invert sugar,” which is what you find in the molasses or refiners syrup added to brown sugar. This invert sugar is actually single monosaccharide molecules that were created by breaking down the double disaccharide molecules that make up granulated or table sugar (sucrose). These monosaccharides possess different chemical properties that make cookies chewier, as we’ll see in the tip below.

Why the different bake time?

By adding extra sugar, you can bake the cookies to a slightly higher temperature without over-baking, which will allow for a crispier final cookie as well as deeper flavor development.

Why not just bake any version longer to get a crunchy cookie without added sugar?

While it’s certainly true that baking any cookie longer will cause it to have a firmer final texture, having the extra granulated sugar allows the cookie to maintain a tender, “snappy,” crisp texture (due to the properties discussed above), as opposed to a less enjoyable hard/crunchy texture.

 

Cookie Science via @kingarthurflour

How to make extra-chewy cookies

Add 2 tablespoons brown sugar.

What does extra brown sugar do to the dough?

While brown sugar is similar to granulated sugar in many ways, it has one major functional component that granulated sugar does not: invert sugar!

The two primary invert sugar monosaccharides found in brown sugar are glucose and fructose, which are actually bound together to make the disaccharide sucrose which is what Americans know as our standard white table sugar.

Compared to sucrose, invert sugars caramelize at a lower temperature, and absorb and retain more moisture; fructose is particularly hygroscopic, meaning it really loves to suck up and hold onto water.

Invert sugars also interfere with recrystallization upon cooling, which helps make cookies crisp. By holding that extra moisture and delaying the sugar’s recrystallization, brown sugar has the wonderful ability to give you a moist, tooth-packing, bendy cookie loved by chewy cookie fans around the world.

Does it make the cookie extra sweet?

While a particularly perceptive taster might be able to tell the difference in sweetness with the additional two tablespoons brown sugar, the overall sugar level increased by less than 20%; so it’s really just a delightfully sweet cookie at either level.

Do light and dark brown sugar work the same?

In fact, they do. The differences between light and dark brown sugar in terms of the amount or types of syrup used are usually minimal, even though you might expect otherwise given the significant difference in coloration.

Cookie Science via @kingarthurflour

How to make extra-cakey cookies

Add 2 tablespoons milk.

What does the extra milk do to the dough?

Although it may seem obvious, the most important role extra milk plays is adding a little more liquid. As cookie dough is very low hydration, that two tablespoons of milk has more of an impact here than it would in something with higher hydration, such as cake batter.

Milk is around 85% water – and that water will evaporate in the heat of the oven to form steam. This steam will migrate to air pockets created by the melting sugar grains.

As the steam gets hotter, it teams up with gases produced by the leaveners, expanding those air pockets. That expansion causes the cookies to puff and rise in the oven, creating an airy, cakey texture.

The moisture contributed by the milk will also increase spread and hydrate more of the starches in the flour. These hydrated (gelatinized) starches support the structure of the air pocket wall, keeping the cookies from collapsing once cooled. By holding more water, they also help keep the cookies softer over time.

Why milk and not water?

While milk is mostly water, those other little molecules in milk do serve a purpose. First, their presence means that there’s 15% less liquid being added to the dough, and this helps prevent the dough from spreading too far and turning into some less-than-ideal chocolate chip pancakes in the oven.

The proteins in milk – about 3% to 4% – will enhance Maillard reactions (as discussed above) and contribute many of the flavor notes that we recognize as “baked,” giving the cookies their roasted, toasted, and even sometimes nutty notes.

Finally, the fat and sugar from the milk also add extra tenderness and richer flavor.

Cookie Science via @kingarthurflour

Some extracurricular reading on cookies science

So there you have it – the cookie science behind transforming our standard chocolate chip cookie mix into crunchy, chewy, or cakey versions. I’m fortunate to be able to share the kitchen with King Arthur’s research and development team, and I have to say that I’m personally just blown away with how good they are at their jobs.

I also want to thank Paula Figoni for her awesome book “How Baking Work” and Harold McGee’s “On Food and Cooking.” Both were enormously helpful.

Happy Baking!

Gwen Adams
The Author

About Gwen Adams

Gwen Adams grew up in northern New Hampshire, on top of a mountain, surrounded by nature and not much else. After graduating from Lyndon State College in 2010, Gwen sought a career that combined her passion for writing with her love of baking. She found it at King Arthur Flour, where she currently happily spends her work hours on our magazine, Sift, as well as blogging, creating recipes, social media, and marketing.